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[Paper认证] Total Synthesis of (-)-Elegansidiol by Using an Abnormal Beckmann Fragmentation of Hajos Ketone Oxime as a Key Step

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1^# 大中小发表于 2008-1-14 12:29 只看该作者 看帖回帖是一种美德,您的回帖是对楼主最大的支持.

Total Synthesis of (-)-Elegansidiol by Using an Abnormal Beckmann Fragmentation of Hajos Ketone Oxime as a Key Step

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姓名	Jianwei Sun
所在学校或单位	Tsinghua University
文章题目	Total Synthesis of (-)-Elegansidiol by Using an Abnormal Beckmann Fragmentation of Hajos Ketone Oxime as a Key Step
期刊名	Tetrahedron
年份，卷（期），起止页码	2007, 63, 5036-5041
影响因子	2.817
文章链接	http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6THR-4NB99BR-3&_user=5745&_coverDate=06%2F04%2F2007&_rdoc=25&_fmt=full&_orig=browse&_srch=doc-info(%23toc%235289%232007%23999369976%23651469%23FLA%23display%23Volume)&_cdi=5289&_sort=d&_docanchor=&view=g&_ct=35&_acct=C000001358&_version=1&_urlVersion=0&_userid=5745&md5=7dc0c0f8323201ee5866343f20173da2

Abnormal Beckmann fragmentation of Hajos ketone oxime regioselectively forms of a chiral 1-oxygenated 2,2-dimethyl-4-methylene-cyclohexan skeleton. Using this transformation as a key step, the total synthesis of (−)-elegansidiol, an oxygenated mono-carbocyclic sesquiterpenoid, was achieved.

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Mcdull 在2008-1-14 12:38 评分： Vip +2.817 原因： Thx for your application for qualified member and welcome to join chem8. If interested, could you share with us the story of this paper at http://chem8.org/bbs/forum-46-1.html?
Mcdull 在2008-1-14 12:38 评分：金币 +100 原因： Thx for your application for qualified member and welcome to join chem8. If interested, could you share with us the story of this paper at http://chem8.org/bbs/forum-46-1.html?

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2^# 大中小发表于 2008-1-14 12:37 只看该作者 查阅本站最新书籍

one more paper, please upgrade me to registered?

Au- and Pt-Catalyzed Cycloisomerizations of 1,5-Enynes to Cyclohexadienes with a Broad Alkyne Scope. J. Am. Chem. Soc. 2006, 128, 9705-9710

http://pubs.acs.org/cgi-bin/abst ... /abs/ja063384n.html

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Mcdull 在2008-1-14 12:41 评分：金币 +1 原因： Following the link at http://chem8.org/bbs/forum-32-1.html to update your account, thx.

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[Paper认证]Selective Oxidation of Polyfunctional 2-Amino-1,3-propanediol

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[Paper认证] Total Synthesis of (-)-Elegansidiol by Using an Abnormal Beckmann Fragmentation of Hajos Ketone Oxime as a Key Step

Total Synthesis of (-)-Elegansidiol by Using an Abnormal Beckmann Fragmentation of Hajos Ketone Oxime as a Key Step

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one more paper, please upgrade me to registered?

[Paper认证]Selective Oxidation of Polyfunctional 2-Amino-1,3-propanediol

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